Season 1 |
| 1 :01x01 - Episode 101 (Oct/13/2006) | | Brian DeCato of Parkland, Washington and Christine Tarbet of Youngstown, Ohio compete in the premiere episode. Members of the mob include Ken Jennings ("Jeopardy!"), valedictorians, and "Deal or No Deal" models. | | Guest Stars: Ken Jennings (3) as Himself | |
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| 2 :01x02 - Episode 102 (Oct/20/2006) | | Christine Tarbet of Youngstown, Ohio returns to try and finish off the mob, and Aaron Sanderlin of Brooklyn, New York and Chaz Hales of Las Vegas, Nevada try their luck to outsmart the mob, which includes brain surgeons, Mensa members and Los Angeles Clippers cheerleaders. | |
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| 4 :01x04 - Episode 104 (Nov/03/2006) | | Ed Brown of Afton, Wyoming returns to try and finish off the mob, and Kelly Ross of Oak Park, California and Monique Soltani of Hollywood, California try their luck to outsmart the mob, which includes Guinness World Book of Records title holders and summa cum laude graduates. | |
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| 5 :01x05 - Episode 105 (Nov/10/2006) | | Monique Soltani of Hollywood, California returns to try and finish off the mob and then Jonathan Kehoe of Cherry Hill, New Jersey gets his chance at the million dollar payoff. | |
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| 6 :01x06 - Episode 106 (Dec/01/2006) | | Jay Stakelon of Allentown, Pennsylvania will play for a special top prize of $3 million as he challenges the mob. | | Guest Stars: Brad Rutter as Himself | |
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| 7 :01x07 - Episode 107 (Dec/08/2006) | | Paula Russell of Chicago, Illinois return to try and finish off the mob and then Molly Garner of Tustin, California will play for a top prize of $1 million against the mob. | | Guest Stars: Brad Rutter as Himself, Annie Duke as Herself, Bob Eubanks as Himself | |
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| 9 :01x09 - Episode 109 (Dec/25/2006) | | In a special Christmas episode, Melanie Pino of Las Vegas, Nevada and Michael Zajaczkowski of Jersey City, New Jersey get their shot at the million dollar prize versus the mob. | | Special Guest Stars: Danny Bonaduce as Himself | |
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| 10 :01x10 - Episode 110 (Jan/05/2007) | | Cari Sudmeier of Palm Desert, California and Barry Lander of San Diego, California challenge the mob for a chance at winning a million dollars. | | Guest Stars: Adam West as Himself (Mob Member) | |
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| 11 :01x11 - Episode 111 (Jan/12/2007) | | Barry Lander of San Diego, California returns to try and finish off the mob and Kwame Horne of Detroit, Michigan face the mob for a million dollar payoff. | | Guest Stars: Fabio as Himself (Mob Member) | |
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| 12 :01x12 - Episode 113 (Jan/19/2007) | | Kwame Horne of Detroit, Michigan returns to try and finish off the mob and Shelly Rego of Sommerville, Massachusetts and Radjiv Ladva of Birmingham, England all get their shot for the million dollar payoff. | | Guest Stars: Fabio as Himself (Mob Member), Judge Joe Brown (1) as Himself (Mob Member) | |
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| 13 :01x13 - Episode 114 (Jan/26/2007) | | Radjiv Ladva of Birmingham, England returns to try and finish off the mob and Janice Carlton of Fort Dix, New Jersey will face off against the mob. | |
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| 15 :01x15 - Episode 115 (Feb/09/2007) | | In a special episode of 1 vs. 100, one mob member is guaranteed to win $250,000 if they can beat all the other Mod Members and be the last mob member standing. Amy Duke was chosing to play as the contestant; playing against a mob including previous mob members including Ken Jennings. | | Guest Stars: Ken Jennings (3) as Himself (Mob Member), Annie Duke as Herself (Mob Member), Brad Rutter as Himself, Nancy Christy as Herself | |
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| 16 :01x16 - Episode 116 (Feb/16/2007) | | Raul Torres of Van Nuys, California and Casey Smith of Des Moines, Iowa play against the mob for a million dollars. | |
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| 17 :01x17 - Episode 118 (Feb/23/2007) | | Joanne Uy of Northridge, California, Herman Wilkins of Chicago, Illinois and Lou Siville of Shiloh, Illinois each have their chance at facing the mob for one million dollars. | |
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| 18 :01x18 - Episode 119 (Mar/02/2007) | | Carolyn Granado of Carlsbad, California and Andrew Murray of Stony Point, New Jersey face the mob for the huge million dollar payoff. | |
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| 19 :01x19 - Episode 120 (Mar/09/2007) | | Mike Korich of Dacula, Georgia and Heather Spanbauer of Modesto, California battle the mob for a million dollar prize. | |
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| 20 :01x120 - Episode 112 (Mar/16/2007) | | Mike Korich of Dacula, Georgia and Heather Spanbauer of Modesto, California, challenge the mob for a chance at the million dollar prize in the season one finale. | |
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Season 2 |
| 21 :02x01 - Episode 201 (Jan/04/2008) | | Actor Barry Williams and actress Dawn Wells make guest appearances on this episode. | |
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| 22 :02x02 - Episode 202 (Jan/11/2008) | | Contestants hailing from Baltimore and Brooklyn take on the mob which contains actress Sommore, Ross Mathews (Tonight Show), Richard Rubin (reality personality) and Oscar the Grouch (Muppets). | |
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| 23 :02x03 - Episode 203 (Jan/18/2008) | | A contestant from Brooklyn takes on "the Mob," consisting of Sommore, Ross "The Intern" Mathews, Richard Rubin and Oscar the Grouch. Also, a woman from Chicago gets her turn as a contestant. | |
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| 24 :02x04 - Episode 205 (Jan/25/2008) | | A thinking man from Montana will take on a single mom from California, versus the mob. | |
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| 26 :02x06 - Episode 207 (Feb/08/2008) | | Contestants from Ohio and Los Angeles take on the mob. Also, a special appearance by Jeremy Miller and Charlene Tilton. | |
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| 27 :02x07 - Episode 208 (Feb/15/2008) | | An expert at pop culture trivia from L.A. and a beauty queen from Texas are this week's contestants against the mob. | |
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| 28 :02x08 - Episode 204 (Feb/22/2008) | | A woman from Chicago returns to challenge the mob as season 2 comes to a close. | |
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