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After being booted out of the Joker's service, Harley Quinn forms a partnership with Poison Ivy. By day, they're house mates and best pals, by night, they're a deadly duo, billed 'The New Queens of Crime' by the Gotham tabloids. The Joker has a fit when he hears of their "Thelma and Louise"-style crime spree, and sets out to get Harley (and more important, the loot she stole) back. Batman has also figured out where the girls are, and both he and the Joker arrive at Ivy's hideout (a model house built over a toxic waste dump) to have it out with them. In an explosive battle Batman takes out the Joker and his men, but a surprise assist from Officer Montoya helps the Dark Knight finally collar Harley and Ivy.
This episode marks the first Harley/Ivy team up, a combination that proved so successful they were to team up again a number of times in the DC animated universe as well as getting their own comic miniseries
Joker: Ahh! The wind in my hair and the Batman at my heels! It's the kind of night that makes you glad to be alive!
Joker: What's going on Rock? The place is a mess, no one has fed the hyenas and I can't find my socks. Where's Harley?
Rock: You canned her boss, remember?
Joker: So? She's always come back before.
Rock: I guess you ain't seen the papers then.
Joker: Papers? What are you babbling about? (Looks at the newspaper that says New queens of crime with Harley and Poison Ivy on the cover) AAAAAAAAH!
Poison Ivy: (As Harley and Ivy make their escape from the burning toxic waste dump) No man can take us prisoner!
(A tire on their car goes flat and they crash on the side of the road. Officer Renee Montoya, who has been watching the fire from down the road approaches the car.)
Officer Renee Montoya: Alright ladies, raise them.
The Joker: That's it. Next time I start a gang, no women! YOU HEAR ME? NO WOMEN!!!
Harley Quinn: Hey aren't you that plant lady... Poison Oaky?
Poison Ivy: IVY! Poison Ivy!